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Figure 9


Fig. 9. Testing the sensitivity of Model A [through the distribution coefficient log10(Kd)] to the value of proportionality factor FW at various values of surface charge (Z). The free Cd ion concentration was 1.00 x 10–8 M; pH = 5.50; ionic strength was 0.01 M (NaNO3); total carboxyl group concentration (TC) was 3.13 molc kg–1. The values of constants and parameters used for Cd were: –log intrinsic stability constant for metal complexation to a monodentate carboxyl binding site = 0.290, –log intrinsic stability constant for metal complexation to a monodentate phenolic hydroxyl binding site = 4.76, proportion of carboxyl groups capable of forming bidentate chelates = 0.051, and proportion of monodentate binding carboxyl groups capable of forming bidentate chelates to a phenolic hydroxyl group = 0.951.