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Published in Soil Sci Soc Am J 22:511-513 (1958)
© 1958 Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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Some Equilibrium Solution Studies on Rothamsted Soils1

A. Wormald Taylor2

ABSTRACT

Experiments designed to determine the variation in composition of solutions brought into equilibrium with samples of four different soils at widely different electrolyte concentrations are described in detail. The ratio law relationship between the potassium and calcium ion concentration
Figure 1
is found to be strictly obeyed only in soils of low potassium status. Variations observed in soils which have received large dressings of potassium fertilizer are attributed to an exchange reaction by which the amount of potassium in readily exchangeable form is increased as the electrolyte concentration is raised.


NOTES

1 Presented before Div. II, Soil Science Society of America, Nov. 18, 1957, at Atlanta, Ga.

2 Research Chemist, Division of Chemical Development, Tennessee Valley Authority, Wilson Dam, Ala. The work recorded in this paper was undertaken while the author was a member of the staff of the Chemistry Department, Rothamsted Exp. Sta., Harpenden, England. The author wishes to acknowledge his debt to Dr. R. K. Schofield, of the University of Oxford, for his advice and interest during the course of this work.

Received for publication December 12, 1958. Accepted for publication May 19, 1958.







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