SSSAJ Journal of Natural Resources and Life Sciences Education
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Published in Soil Sci Soc Am J 29:487-488 (1965)
© 1965 Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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Hydrolysis of Condensed Phosphates in Soils1

R. R. Allmaras

Soil and Water Conservation Research Division, ARS, USDA, at Morris, Minnesota

C. A. Black, former Graduate Assistant, now Soil Scientist, Professor of Soils

Iowa State University

ABSTRACT

Hydrolytic degradation of the condensed phosphates of fertilizer-grade calcium metaphosphate (CMP) in soils involves several steps, including formation of a dense, viscous liquid from the vitreous portion of the CMP. Experiments indicate that the rate-controlling step in the early stages of transformation of condensed P to orthophosphate in soils treated with solid particles of CMP was the degradation of the viscous liquid and not the hydrolysis of the condensed P in the solution derived from the viscous liquid.


NOTES

1 Journal Paper no. J-4143 of the Iowa Agr. and Home Econ. Exp. Sta., Ames, Iowa. Project no. 1183. Contribution from the Department of Agronomy. This work was conducted in cooperation with the Division of Agricultural Relations, Tennessee Valley Authority.

Received for publication January 6, 1965. Accepted for publication March 26, 1965.







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Copyright © 1965 by the Soil Science Society of America.