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Forestry Sciences Lab., Boise, ID 83702
College of Idaho, Caldwell, ID
*Corresponding author.
ABSTRACT
Both base exchange and SO4 adsorption were important proton consuming processes in a laboratory leaching study of western, high-elevation Inceptisols. Two soils formed from granitic parent materials are present in the watershed: a highly organic Humic Cryaquept (HCA) located adjacent to streams and on lake margins, and an upland Dystric Cryochrept (DCO). Large, single-horizon soil columns were leached sequentially with deionized H2O (six pore volumes [PV]), pH 4 H2SO4 (12–16 PVs), and pH 3 H2SO4 (11–16 PVs). These treatments were equivalent to 3 to 6 yr of runoff and 50 to 100 times annual S-deposition rates. Proton exchange for base cations was very effective at buffering all horizons for the distilled H2O and pH 4 treatments. Following three to five PVs of pH 3 H2SO4, leachate pH dropped to 5 in the B horizon and 4.2 in the C horizon of the DCO. The Al(OH)3 dissolution then stabilized the pH in those two experiments. The A horizon of the DCO and both HCA horizons had sufficient cation-exchange capacity (CEC) and base saturation to resist large pH depressions during the pH 3 treatment. Cation exchange was the dominant neutralization process, accounting for 56 to 96% of total proton consumption. Sulfate adsorption was important in DCO horizons (20–35% of protons consumed), but not in the organic HCA soil. Postleaching analysis of soils indicated that exchangeable Na and Mg decreased to about one-half of original values, but Ca and K remained unchanged. Apparently, hydrolysis of abundant primary minerals can resupply these cations under the conditions of these experiments.
Contribution from the Intermountain Res. Stn., U.S. Forest Service, Ogden, UT 84401.
Received for publication October 15, 1990.
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