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Supercritical Fluid Extraction of 2,4-D from Soils: pH and Organic Matter Effects

Dep. of Plant, Soil and Entomological Sciences, Univ. of Idaho, Moscow, ID 83344-2339

J. B. Harsh

Dep. of Crop and Soil Sciences

H. H. Hill, Jr.

Dep. of Chemistry, Washington State Univ., Pullman, WA 99164

*Corresponding author (rochette{at}uidaho.edu).

ABSTRACT

Supercritical fluid extraction (SFE) recoveries of 2,4-D (2,4-dichlorophenoxyacetic acid) from spiked Washington soils depended on both pH and organic matter content. The soils used in this study spanned a wide range of organic C concentration (2–480 g kg^–1). One of the soils (the Benge series A horizon) was adjusted to pHs from 1.8 to 8.3, and extracted with methanol-modified supercritical CO₂. Recoveries from this soil increased from 41 to 76% with decreasing pH. For soils at natural pHs, when a weak acid modifier (benzoic acid) was used in addition to methanol, the 2,4-D recovery ranged from 21 to 86%, increasing with decreasing organic C concentration. Treating the samples to the lowest pHs practical (1.2–1.6) with HCl and extracting with methanol-modified supercritical CO₂ was more successful than utilizing the weak acid-methanol modifier, except for the soil with very low organic C. Recoveries after HCl treatment ranged from 80 to 94%. Two soils from 2,4-D-treated fields yielded more 2,4-D by modified SFE at pH 1.2 than by a modified version of the method recommended by the U.S. Environmental Protection Agency. The results suggest that organic acids like 2,4-D can be successfully extracted at low pH, even from soils high in organic C. Low recoveries from soils high in organic C appear to result from proton consumption by natural soil organic matter during extraction.

Received for publication February 24, 1997.