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Fig. 1. Manganese-x-ray absorption near edge structure (XANES) spectra for aqueous MnSO₄, Mn(III)-pyrophosphate, synthetic birnessite, eight recently air-dried, high Mn soils, and synthetic pyrolusite. Successive spectra are offset by 0.2 relative intensity. Energy is relative to the pre-edge peak of a Mn(VII) standard.